Natural Water Photochemistry: Singlet Oxygen Production and the Degradation of Dissolved Organic Nitrogen and Organic Pollutants

Natural Water Photochemistry: Singlet Oxygen Production and the Degradation of Dissolved Organic Nitrogen and Organic Pollutants
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Published on 2008 by ProQuest

Structure Energetics and Reactivity in \u003cb\u003eChemistry\u003c/b\u003e Series 1995, 2, (Active Oxygen \u003cbr\u003e\nin \u003cb\u003eChemistry\u003c/b\u003e), 280-333. 29. Zepp, R. G., \u003cb\u003eEnvironmental\u003c/b\u003e photoprocesses involving \u003cbr\u003e\nnatural \u003cb\u003eorganic\u003c/b\u003e matter. Life Sciences Research Report 1988, 41, (Humic Subst.

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The 1O2-mediated degradation of a class of organic pollutants known as the nitrofuran antibiotics was also investigated. These compounds were expected to degrade, at least in part, through reaction with 1O2 due to their 1O2-reactive furan ring. In fact, degradation was found to be due solely to direct photolysis, with half-lives for the compounds ranging from 5-26 minutes in mid-summer at 45° latitude.

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